A metal-covalent organic framework catalyst with pincer coordination units for boosting transfer hydrogenation of quinolines with ammonia borane

Wenying Ai, Xiao Du,Yu Yang,Zelin Zheng,Lipeng Zhai,Baiwei Ma,Siwen Cui,Pengyu Li,Liwei Mi,Lingbo Qu

JOURNAL OF MATERIALS CHEMISTRY A（2022）

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摘要

A crystalline 2D nickel-coordinated bis(imino)pyridine metal-covalent organic framework (Ni-bipy-COF) material is easily fabricated by incorporating nickel ions into the bis(imino)pyridine pincer COF skeleton. The Ni-bipy-COF catalyst can be applied to catalyze the transfer hydrogenation of quinolines with ammonia borane as a hydrogen source.

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关键词

organic framework catalyst,transfer hydrogenation,ammonia borane,organic framework

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