1H Time Domain NMR to probe microstructural and mobility changes in Polyamide 11 exposed to H2S scavengers. What type of information can be assessed?

Polymer Degradation and Stability(2022)

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摘要
•H2S ethoxylated scavenger induces motional hindrance in the amorphous phase of PA11.•Time domain NMR methods are effective for detecting the effect of H2S ethoxylated scavenger in the microstructure of PA11.•Permanent crosslinks among PA11 results from the exposure to ethoxylated scavengers.
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关键词
Polyamide 11,H2S scavenger,Flexible oil pipelines,Time domain nuclear magnetic resonance,Crosslinks,Dynamical constrains
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