The tuning of oxalato-bridge on magnetic interaction and field-induced phase transition in Ba2Co2Cl2(C2O4)3·4H2O

Yujie Song,Haoyu Niu,Zhuo Zeng,Dequan Jiang,Youyuan Liang,Hao Huang,Lixia Xiao,Zhengcai Xia

Journal of Magnetism and Magnetic Materials（2022）

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摘要

•The high field magnetization of Ba2Co2Cl2(C2O4)3·4H2O performs clearly magnetic phase transition behavior around 6 T.•Two kinds of spin-dimers with different intra- and inter-interaction can be assumed by Bleaney-Bowers fitting.•The experimental results confirm that different bridging modes which form different spin dimers, play an important role in tuning the interaction of the dimer.

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关键词

Oxalato-bridged,Spin dimer,Phase transition,Pulsed high magnetic field

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