Applying the B/N Lewis Pair Approach to Access Fusion-Expanded Binaphthyl-Based Chiral Analogues.
Inorganic chemistry(2022)
摘要
We herein describe the synthesis of two axially chiral systems ( and ) by the incorporation of B centers into binaphthyl derivatives ( and ). Heteroatom-doped chiral polycyclic aromatic hydrocarbons were thus formed by fusion of the azaboroles to binaphthyls with the formation of B-N dative bonds. The resulting B-N Lewis pairs that serve as attractive fluorophores enabled modulation of the chiroptical properties both in solution and in the solid state.
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关键词
fusion-expanded,binaphthyl-based
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