Infrared quantification of ethanol and 1-butanol hydrogen bonded hydroxyl distributions in cyclohexane

William G. Killian,Aseel M. Bala,Andrew T. Norfleet,Lars Peereboom,James E. Jackson,Carl T. Lira

Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy（2023）

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摘要

•The concentration of hydrogen-bonded hydroxyls are inferred from temperature-variant infrared measurements.•RTPT parameters were regressed for ethanol and 1-butanol in cyclohexane and the average chain length was found to be similar.•Enthalpies are tabulated for the formation of dimer and n-mer oligomers and compared to the hydrogen bond dispersion energy.

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关键词

Quantitative infrared spectroscopy,Hydrogen bonding,Beer’s law,Beer-Lambert law,Wertheim association

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