N-ethyltetramethylguanidinium ionic liquid [ETMG][EtSO3] as organocatalyst and solvent for facile amide synthesis by formyl-transfer with N-formyl-saccharin

Shruti S. Malunavar,Athmanand Anchi, Pavankumar Prabhala,Rajesh G. Kalkhambkar,Gabriela L. Borosky,Kenneth K. Laali

Tetrahedron Letters（2022）

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摘要

•Facile access to structurally diverse formamides.•An acid and metal free process.•[ETMG][EtOSO3] IL as organocatalyst and solvent.•Formyl-SAC as formyl transfer reagent.•Recycling/reuse of the organocatalyst.

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关键词

Amide synthesis,N-formyl-SAC,N-ethyltetramethylguanidinium salt as organocatalyst,Recycling/reuse,DFT computations

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