Micro- and nano-fibrils of manau rattan and solvent-exchange-induced high-haze transparent holocellulose nanofibril film
Carbohydrate Polymers(2022)
摘要
Holocellulose nanofibrils (HCNFs) are nanoscale objects extracted from biomass resources and have attracted attention as sustainable building blocks for nanomaterials. In this study, we report a top-down approach for extracting HCNFs from manau rattan that involves pulping, bleaching and TEMPO oxidation. The extracted HCNFs showed a uniform width of around 18.5 nm and a length of a few micrometers, high crystallinity (66.5 %), and good thermal stability (302 °C). The extracted HCNFs were used to fabricate HCNF film via vacuum filtration and drying (air drying and solvent exchange drying). Surprisingly, the HCNF film fabricated by solvent exchange drying (HCNF-filmSD) simultaneously presented a high total transmittance (93.7 %) and high haze (62.2 %), and its total transmittance was even higher than that of glass. The resulting HCNF-filmSD displayed a high tensile strength (84.8 MPa), Young's modulus (3.7 GPa), and toughness (1.4 MJ m−3), making it a high-performance and eco-friendly film for applications in precision optoelectronics and aerospace materials.
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关键词
Holocellulose nanofibrils (HCNFs),Transmittance,Haze,HCNF film,Solvent-exchange drying
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