Bluff-body MILD combustion regime for semicoke and bituminous coal mixtures with effect of oxidizer O2 concentration in O2/N2 and oxy-fuel (O2/CO2) atmospheres

Fuel(2023)

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摘要
The present study numerically investigates the effects of the O2 content (XO2) in the oxidizer on the MILD combustion behaviours of large-proportion semicoke mixtures, such as those involving temperature, MILD regime recognition, char surface consumption, homo/heterogeneous Damkhöler number, and NOx emission, under O2/N2 and O2/CO2 atmospheres. The results indicate that by increasing XO2 from 15 % to 30 %, the peak temperature increases significantly due to the increased char consumption rate, the high temperature region shrinks, and the axial length of the MILD regime region slightly increases from ∼1 to ∼1.4 m because of enhanced flue gas recirculation under O2/N2 or O2/CO2 atmosphere. The reduction effects of the char-O2 reaction proportions and the promoted effects of the char-CO2 reaction proportions due to the increased XO2 are both obviously weakened when N2 is substituted for CO2. A high O2 content and an O2/N2 atmosphere reduce the char burnout time. With increasing XO2, the maximum value of the turbulent Damkhöler number Dat increases from 6.79 to 10.16 under the O2/N2 atmosphere and from 3.99 to 10.6 under the O2/CO2 atmosphere, implying that a low O2 dilution and a CO2 environment promote the establishment of the homo-MILD regime. The maximum values of the surface Damkhöler number (Das-CO2 and Das-H2O) of the two gasification reactions (Char-CO2 and Char-H2O) have the same order of magnitude and are much lower than those of the surface Damkhöler number (Das-O2) of the Char-O2 oxidation reaction, i.e., Das-H2O < Das-CO2 ≪ Das-O2 < 1. The maximum values of the three surface Damkhöler numbers all increase with increasing XO2, while they decrease with the replacement of N2 by CO2, indicating that a high O2 content and an O2/N2 atmosphere could facilitate the establishment of an ideal hetero-MILD combustion regime to some extent. Low NOx emissions can be realized under moderate O2 and CO2 dilution conditions by regulating the oxy-MILD combustion regime of semicoke blends.
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关键词
Homo/hetero-MILD combustion,Char surface reaction,O2 content,CO2 dilution,NOx emission
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