Tris(trifluoromethyl)germyl biphenyl conjugated molecular system with ferrocenyl substituent: Confirmation of photoinduced intramolecular charge transfer to the germanium center

Nikolai L. Ermolaev,Georgy K. Fukin,Andrei S. Shavyrin,Mikhail A. Lopatin,Olga V. Kuznetsova, Denis I. Kryzhkov,Stanislav K. Ignatov, Evgeniy P. Chuhmanov,Nadezhda T. Berberova,Konstantin P. Pashchenko

Journal of Organometallic Chemistry（2023）

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摘要

•New tris(trifluoromethyl)germylethynyl derivative of biphenyl with ferrocenylethnyl donor group have been prepared.•Intramolecular energy and electron transfer have been investigated in the unsymmetrical 4-ferrocenylethnyl-4´-[tris(trifluoromethyl)germylethynyl]biphenyl molecule.•Vacant Ge 4d atomic orbitals play a key role in this phenomenon.

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关键词

Germanium,Perfluoroalkyl,Conjugation,Excited state,Charge transfer,Radical-ion pair,Electronegativity

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