Chiral Smart Bionic Skin Film with Changeable Structural Colors and Tunable Luminescence by Polymer-Assisted Supramolecular Assembly of the Photonic Crystals
Applied materials today(2022)
摘要
The biological skin system of advanced organisms can obtain various environmental stimuli to change skin colors by adjusting the micro-nano structure of the skin surface or by electroluminescence and photoluminescence. The assembly of biominetic skin materials with both changeable structural colors and tunable luminescence is a significant challenge in the fields of advanced materials and light science. This work describes a novel chiral smart bionic skin film with changeable structural colors, tunable luminescence by the polymer-assisted supra -molecular assembly of the photonic crystals. A smart nanodot based on the molecule with four-armed mimosa -like structure was assembled on the cellulose nanocrystals (CNC) photonic crystal. The chiral bionic skin film obtained had multi-channel fluorescence-emission, sensitive structural color stimulus responses to the light and humidity and the tunable chiral helical nematic domains. It demonstrates a series of the supramolecular in-teractions that trigger multiple intelligent signals, including the adjustable chiral pitch, photo-induced electron transfer (PET), intramolecular fluorescence resonance energy transfer (FRET), 7C -7C stacking and the changes of the hydrogen bonds. The photonic crystal skin materials with sensitive multi-signals intelligent responses as smart bionic skin have potential applications for the tissue engineering, 3D printing materials, bionic artificial skin materials, and optical devices.
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关键词
Chiral fluorescent membrane,Multi -channel switches,Self -assembly,Tunable structure color,Intelligent response
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