The unique role of pore wall nanostructurization in the intrachannel photo-ATRP for fine-tuning PMMA tacticity

Paulina Maksym,Roksana Bernat,Kajetan Koperwas,Marcin Wojtyniak, Julita Piecha,Barbara Hachula,Monika Geppert-Rybczynska,Agnieszka Brzozka,Grzegorz D. Sulka,Magdalena Tarnacka,Marian Paluch,Kamil Kaminski

CHEMICAL COMMUNICATIONS（2022）

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摘要

In this paper, efficient MMA photo O-ATRP protocols conducted inside nanoreactors varying in nanostructured interfaces are reported for the first time. We showed that the microstructure of recovered polymers could be easily tuned just by implementing a given type of nanochannel (d = 10, 19-28, 35, 160 nm).

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关键词

pore wall nanostructurization,pmma tacticity,photo-atrp,fine-tuning

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