Suppressing the donor-like effect via fast extrusion engineering for high thermoelectric performance of polycrystalline Bi2Te2.79Se0.21

Bi2Te3-based alloys are the most mature commercial thermoelectric (TE) materials for the cooling application near room temperature. However, the poor mechanical properties of the commercial zone melting (ZM) ingot severely limits the further application. Meanwhile, due to the donor-like effect, the robust polycrystalline n-type bulks usually have low TE performance near room temperature. Herein, based on the commercial ZM ingots, a high figure of merit (zT) of 1.0 at 320 K and good mechanical properties are achieved via the hot extrusion. The dynamic recrystallization in the hot-extrusion process can suppress the donor-like effect and refine the large ZM grains into fine-equiaxed grains. Moreover, the obtained polycrystalline Bi2Te2.79Se0.21 has good preferential orientation and high carrier mobility (m). The high m and the weaken donor-like effect maintain the high power factor (PF) of 43.1 mu W cm-1 K-2 in the hot-extruded ZM sample. Due to the enhanced phonon scattering, the total thermal conductivity ktot decreased to 1.35 W center dot m-1 center dot K-1. To demonstrate the good mechanical properties of the extruded ZM sample, micro TE dices with the cross sections of 300 mu m x 300 mu m and 200 mu m x 200 mu m are successfully cut from the extrusion sample. This study provided a fast and low-cost extrusion technique to improve the TE and mechanical properties of the commercial ZM ingot at room temperature. (c) 2022 The Authors. Published by Elsevier B.V. on behalf of The Chinese Ceramic Society. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).