Unravelling Structures of Radicals of Kynurenic Acid Formed in the Photoinduced Reactions with Tryptophan and N-acetyl Tyrosine

Olga B. Morozova,Maksim P. Geniman,Mikhail S. Panov,Natalya Fishman,Alexandra V. Yurkovskaya,Peter Sergeevich Sherin

Physical Chemistry Chemical Physics（2022）

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摘要

Kynurenic acid (KNA) in the triplet state reacts with tryptophan (Trp) at neutral pH via proton-coupled electron transfer (PCET),1 which includes the stepwise transition of both electron and proton from...

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photoinduced reactions,kynurenic acid,tryptophan,radicals

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