Copper for alkynylallylic substitution

Nature Synthesis（2022）

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摘要

Chiral tetrahedral carbon atoms bearing functional groups amenable to functionalization offer numerous synthetic opportunities. Catalysed by copper pyridine-bis(oxazoline) complexes, the developed alkynylallylic substitution provides 3-substituted 1,4-enynes with excellent regio- and stereocontrol.

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关键词

Asymmetric catalysis,Synthetic chemistry methodology,Chemistry/Food Science,general

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