A redox-active Mn(0) dicarbene metalloradical.

Ageliki Karagiannis,Alexei M Tyryshkin,Roger A Lalancette,Denis M Spasyuk, Asmaa Washington,Demyan E Prokopchuk

Chemical communications (Cambridge, England)（2022）

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摘要

We report a rare redox-active Mn0 metalloradical [Mn(CO)3(Ph2B(tBuNHC)2)]- (NHC = N-heterocyclic carbene) with countercations [K(2.2.2)crypt]+, [Na(2.2.2)crypt]+, or [Li(DME)(12-crown-4)]+ (DME = 1,2-dimethoxyethane), all characterized via single crystal X-ray diffraction. Cyclic voltammograms reveal solvation-dependent MnI/0 redox potentials that are modeled using the Born equation.

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关键词

mn0,redox-active

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