Observation of Rare Tri6Di9 Imine Cages Using Highly Fluorinated Building Blocks

The first synthesis of an organic Tri6Di9 cage is presented. Two structurally distinct Tri6Di9 cages were synthesised by combining a highly fluorinated aldehyde with two ditopic amines. Although the pure compound could not be isolated despite many attempts, the information obtained is critical for the future design of large supramolecular structures. Computational and experimental methods indicate that the addition of perfluorinated aromatic linkers in the assembly of porous organic cages opens up new possibilities for influencing the reaction pathway towards rare and unknown structures.