Synergy of Block Copolymers and Perovskites: Template Growth through Self-Assembly

Block copolymers (BCPs) have been widely used as templates to prepare nanostructures over the past few decades. Ordered nanostructures can be formed after microphase segregation of BCPs. In this context, the newly emerging BCP-templated perovskites, in which the perovskite crystal growth has been confined within a self-assembled BCP nanostructure due to the interaction between the polymer block and the cation of the perovskite, have shown profound optical performance and environmental stability. Considering the promising performance of BCP-templated perovskites, this Perspective comprehensively reviews recent works in which BCPs are used as templates with three-dimensional perovskites and perovskite quantum dots, and their performance and stability are thoroughly discussed. Lastly, their potential applications in optoelectronics and biology are discussed.