Formation of a Meltable Purinate Metal-Organic Framework and Its Glass Analogue.

Alice M. Bumstead,Celia Castillo-Blas,Ignas Pakamore,Michael F. Thorne,Adam F. Sapnik,Ashleigh M. Chester,Georgina Robertson,Daniel J. M. Irving,Philip A. Chater,David A. Keen,Ross S. Forgan,Thomas D. Bennett

Chemical communications（2023）

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摘要

The chemistries that can be incorporated within melt-quenched zeolitic imidazolate framework (ZIF) glasses are currently limited. Here we describe the preparation of a previously unknown purine-containing ZIF which we name ZIF-UC-7. We find that it melts and forms a glass at one of the lowest temperatures reported for 3D hybrid frameworks.

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