Flexible three-dimensional diacetylene functionalized covalent organic frameworks for efficient iodine capture.

The construction of functionalized covalent organic frameworks (COFs) is of great significance for broadening their potential applications, but is yet challenging to achieve, especially for three-dimensional (3D) COFs, because the connection of the building organic skeleton must strictly follow the pre-designed topology. Here we present the synthesis of two diamondyne-like 3D COFs (CPOF-2 and CPOF-3) functionalized with acetylene (-CC-) and diacetylene (-CC-CC-), respectively. The obtained COFs show a high crystallinity, permanent porosity, and chemical stability. Furthermore, CPOF-3 exhibited an extremely high volatile iodine uptake (as high as 5.87 g g), much higher than that of most reported COF-based adsorbents for iodine capture. Therefore, this study provides a new design principle to obtain high-performance iodine loading porous materials to solve the environmental pollution problem caused by radioactive iodine in the waste of the nuclear industry.