Two-dimensional Be 2 Al and Be 2 Ga monolayer: anti-van't Hoff/Le Bel planar hexacoordinate bonding and superconductivity.

Because of the electron deficiency of boron, a triangular network with planar hexacoordination is the most common structural and bonding property for isolated boron clusters and two-dimensional (2D) boron sheets. However, this network is a rule-breaking structure and bonding case for all other main-group elements. Herein, the BeM (M = Al and Ga) 2D monolayer with 6/ space group was found to be the lowest-energy structure with planar hexacoordinate Be/Al/Ga motifs. More interestingly, BeAl and BeGa were observed to be intrinsic phonon-mediated superconductors with a superconducting critical temperature () of 5.9 and 3.6 K, respectively, where compressive strain could further enhance their . The high thermochemical and kinetic stability of BeM make a promising candidate for experimental realization, considering its high cohesive energy, absence of soft phonon modes, and good resistance to high temperature. Moreover, the feasibility of directly growing BeM on the electride CaN substrate was further demonstrated, where its intriguing electronic and superconducting properties were well maintained in comparison with the freestanding monolayer. The BeM monolayer with rule-breaking planar hexacoordinate motifs firmly pushes the ultimate connection of the "anti-van't Hoff/Le Bel" structure with promising physical properties.