Trapping an Unusual Ring-Opened Product of THF within a Lithium Hydrido Aluminate

Matthew J. Evans,Andrea O’Reilly,Mathew D. Anker,Martyn P. Coles

Organometallics（2022）

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摘要

The reduction of Al(NONDipp)I (NONDipp = [O(SiMe2NDipp)2]2–, Dipp = 2,6-iPr2C6H3) using lithium metal in THF solvent afforded the but-3-enyl-1-oxido product Al(NONDipp)(H)(μ-OCH2CH2CHCH2)Li(THF)2. This is the first time that the metalated product of this unusual THF activation pathway has been isolated and structurally characterized.

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lithium,thf,ring-opened

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