Formation of distinct iron hydrides via mechanistic divergence in directed C-H Bond activation of aryl ketones, esters and amides.
Chemical communications (Cambridge, England)(2023)
摘要
Directing groups play an important role in controlling the selectivity of C-H bond activation. Here we demonstrate that for iron, the nature of the directing group (, ketone, ester, or amide) influences the C-H activation process. In this study the C-H bond activation step either occurs with or without the assistance of the directing group resulting in distinct - and -isomers of the corresponding iron hydride.
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关键词
distinct iron hydrides,aryl ketones
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