Broadband high-contrast visible optical s itches based on a spin-crossover material

Visible optical switches embedding a spin-crossover thin film and exploiting the frustrated total internal reflection operation principle are studied and optimized numerically with a view to obtain broadband high-contrast devices. A practical implementation using uncoated SF11 prisms embedding a 1-mu m-thick layer of iron-triazolyl-borate complex as the thereto-active phase-change material is shown to support p-polarized modulation with contrast in excess of 90% over a spectral bandwidth greater than 270 nm and over an angular acceptance bandwidth of 0.45 degrees, surpassing the performance achievable with optically resonant devices. (C) 2022 Optica Publishing Group