Enhanced photocatalytic hydrogen evolution with a Mixed-Valence iron Metal-Organic framework

Chemical Engineering Journal(2023)

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摘要
•A heteroatom-containing Fe MOF with binuclear mixed-valence cluster was synthesized.•The band structure and charge transfer were favorably regulated via valence mixing.•The iron catalyst performs well in facilitating H2 generation under visible light.
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关键词
Iron metal–organic framework,Photocatalyst,Mixed-valence,Heteroatom coordination,Hydrogen evolution
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