Construction of covalent organic frameworks with alternating rigid and flexible units and their controlled release of active sites

Chemical Engineering Journal(2023)

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摘要
•The strategy for the construction of rigid & flexible COFs was proposed.•The flexible units endow COFs with abundant potential active sites.•The active sites can be released in situ through controlled dissociation reactions.•The site-released COFs exhibit significant improvement on adsorption performance.
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关键词
Adsorption,Covalent organic framework,Active site,Controlled release,Rigid and flexible structure
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