The Heterostructures of CuO and SnO_x for NO₂ Detection

Controlling environmental pollution is a burning problem for all countries more than ever. Currently, due to the increasing industrialization, the number of days when the limits of air pollutants are over the threshold levels exceeds 80–85% of the year. Therefore, cheap and effective sensors are always welcome. One idea is to combine such solutions with cars and provide real-time information about the current pollution level. However, the environmental conditions are demanding, and thus the developed sensors need to be characterized by the high 3S parameters: sensitivity, stability and selectivity. In this paper, we present the results on the heterostructure of CuO/SnOx and SnOx/CuO as a possible approach for selective NO2 detection. The developed gas sensors exhibited lower operating temperature and high response in the wide range of NO2 and in a wide range of relative humidity changes. Material characterizations and impedance spectroscopy measurements were also conducted to analyze the chemical and electrical behavior.