Multiple Stimuli-Response Polychromatic Carbon Dots for Advanced Information Encryption and Safety.

Optical information encryption and safety have aroused great attention since they are closely correlated to data protection and information safety. The development of multiple stimuli-response optical materials for constructing large-capacity information encryption and safety is very important for practical applications. Carbon dots (CDs) have many gratifying merits, such as polychromatic emission, diverse luminous categories, and stable physicochemical properties, and are considered as one of the most ideal candidates for information protection. Herein, carbon core, functional groups, solvents, and other crucial factors are reviewed for outputting polychromatic emission of multiple luminous categories. In particular, substrate engineering strategies have been emphasized for their critical role in yielding excellent optical features of multiple luminous categories. High-capacity information encryption and safety strategies are reviewed by relying on the rich optical properties of CDs, such as polychromatic emission, multiple luminous categories of fluorescence, afterglow, and upconversion, as well as external-stimuli-assisted optical changes. Some perspectives for preparing excellent CDs and further developing information security strategies are proposed. This review provides a good reference for the manipulation of polychromatic CDs and the development of next-generation information encryption and safety.