Disposable p-coumaric acid sensor containing reduced graphene oxide, nickel nanoparticles and biodegradable molecularly imprinted polymer for fruit peel analysis
Journal of Food Composition and Analysis(2023)
摘要
This work reports the development of a disposable molecularly imprinted electrochemical sensor based on the electropolymerization of 3-indoleacetic acid on an electrode containing reduced graphene oxide and nickel nanoparticles for the sensitive and selective detection of p-coumaric acid. The molecularly imprinted sensor was characterized by cyclic voltammetry, electrochemical impedance spectroscopy, scanning electron microscopy, energy dispersive X-ray spectroscopy and X-ray photoelectron spectroscopy. The obtained results showed that reduced graphene oxide and nickel nanoparticles increased the sensitivity of the sensor for selective recognition of p-coumaric acid. Under optimal conditions, the developed sensor presented linear concentration ranges from 1.0 × 10−10 to 1.0 × 10−8 mol L−1. The detection and quantification limits calculated for this sensor were 8.1 × 10−11 and 2.7 × 10−10 mol L−1, respectively. The proposed device exhibited excellent selectivity, repeatability and stability over time, as well as good accuracy for the detection of p-coumaric acid. As a proof of concept, the sensor was applied for the determination of this molecule in banana and orange peels. The mean recovery values obtained during the analyses ranged from 96% to 102%, with relative standard deviations of ≤ 4.8%.
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关键词
Disposable molecularly imprinted electrochemical sensor,3-Indoleacetic acid,Reduced graphene oxide,Nickel nanoparticles,p-Coumaric acid,Fruit peels
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