Electrochemical C(sp3)–H Functionalization of Ethersviahydrogen-Atom Transfer by Means of Cathodic Reduction

Leonardo Rapisarda,Andrea Fermi,Paola Ceroni,Riccardo Giovanelli,Giulio Bertuzzi,Marco Bandini

CHEMICAL COMMUNICATIONS（2023）

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摘要

An electrochemical allylation/alkylation of cyclic/acyclic ethers is presentedviaa C(sp3)–H activation, proceeding under cathodic reduction. The reaction shows broad functional group tolerance and high yields.

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关键词

Electrochemical Conversion,C–H Functionalization,C–H Activation,Electrochemical Methods,Transition Metal Catalysis

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