Stepwise Assembly of Heterometallic, Heteroleptic "triblock Janus-type" Metal-Organic Polyhedra
Chemical communications (Cambridge, England)(2023)
摘要
Increasing the chemical complexity of metal-organic cages (MOCs) or polyhedra (MOPs) demands control over the simultaneous organization of diverse organic linkers and metal ions into discrete caged structures. Herein, we show that a pre-assembled complex of the archetypical cuboctahedral MOP can be used as a template to replicate such caged structure, one having a "triblock Janus-type" configuration that is both heterometallic and heteroleptic.
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Metal-Organic Frameworks
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