Halogen Bonding Between Metal-Bound I3− and Unbound I2: the Trapped I2⋯I3− Intermediate in the Controlled Assembly of Copper(i)-Based Polyiodides

Mikhail A. A. Kinzhalov,Daniil M. M. Ivanov,Anastasia V. V. Shishkina,Anna A. A. Melekhova,Vitalii V. V. Suslonov,Antonio Frontera,Vadim Yu. Kukushkin,Nadezhda A. A. Bokach

INORGANIC CHEMISTRY FRONTIERS（2023）

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摘要

The identification of halogen bonded-intermediates is key to understanding the precise mechanism for the generation of I5− (and I82−) ligands from I2 and metal-coordinated I3−.

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关键词

Halogen Bonding,Hydrogen Bonding,Hydrogen Bonding Interactions

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