Hierarchical CdS/Ni 3 S 4 /Ni 2 P@C Photocatalyst for Efficient H 2 Evolution under Visible-Light Irradiation.

ACS applied materials & interfaces(2023)

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Structural and morphological modulations play a crucial role in increasing the surface active sites of semiconductor photocatalysts for visible-light-driven water splitting. To fabricate a novel CdS/NiS/NiP@C heterostructure, we first prepared carbon-encapsulated NiS/NiP (NiS/NiP@C) with a high surface area by sequential carbonization and phosphorization of a Ni-metal-organic framework (MOF) precursor. Combined characterization and photoelectrochemical measurement results reveal that the assembly of CdS nanowires and highly porous NiS/NiP@C can enhance the visible-light response capability of the CdS/NiS/NiP@C heterostructure catalyst by reducing the forbidden band gap of CdS. The hydrogen production rate of 21.56 mmol h g for CdS/NiS/NiP@C with a NiS/NiP@C mass fraction of 10 wt % was 26 times higher than that of CdS in a photolytic aquatic hydrogen system. A possible mechanism for the photocatalytic enhancement of the NiS/NiP@C co-catalyst was systematically investigated and discussed. This research opens a new strategy for constructing ternary heterojunction photocatalysts via MOF precursors.
CdS,Ni-MOF,Ni3S4/Ni2P co-catalyst,heterojunction,photocatalytic hydrogen evolution
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