Petrogenesis of Early Mesozoic volcanic rocks in southeastern NE China: Geochemical and Sr–Nd–Pb–O isotopic evidences

This paper reports a study of whole-rock geochemical, Sr–Nd–Pb isotopic compositions and zircon UPb ages and O isotopic compositions of Late Triassic to Early Jurassic volcanic rocks of the Yanbian–Dongning area, northeastern China. The obtained data are used to constrain the petrogenesis of these rocks and to provide new insights into the timing of transition from the Paleo-Asian to the Paleo-Pacific tectonic regime. The studied Late Triassic to Early Jurassic volcanic rocks can be divided into two periods: Late Triassic–early Early Jurassic (212–198 Ma) and late Early Jurassic (ca. 181 Ma). The former rocks display high SiO2 and total alkalis contents, high Ga/Al ratios, depleted SrNd and highly radiogenic Pb isotopic signatures, and low zircon δ18O values. The former rocks have a genetic relationship with coeval intrusions, and their primitive melt was derived from juvenile crustal materials and underwent subsequent differentiation and assimilation of low-δ18O rocks. In contrast, the latter rocks have SiO2 contents of 49.00–63.30 wt%, are classified as calc-alkaline, and display arc-type trace-element features. Their geochemical and Sr–Nd–Pb–O isotopic compositions imply derivation from the partial melting of depleted mantle wedge metasomatized by oceanic slab-derived fluid and sediment melt. Combining these new results with published data, the Late Triassic–early Early Jurassic volcanic rocks are inferred to have formed in a rift-like extensional setting, whereas the late Early Jurassic volcanic rocks were generated in a subduction-related setting. The transition from the Paleo-Asian to the Paleo-Pacific tectonic regime occurred during the Early Jurassic.