Tromancenium complexes with steric and electronic modulation

Anna Pavun,Holger Kopacka,Klaus Wurst,Thomas Müller,Florian R. Neururer,Stephan Hohloch,Benno Bildstein

Journal of Organometallic Chemistry（2023）

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摘要

•New series of highly substituted cymantrene and tromancenium complexes.•First indications of reversible redox chemistry in tromancenium chemistry.•Characterization of all complexes by 55Mn NMR spectroscopy and determination of the substitution pattern on the electronic structure of the manganese(I) atom.

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关键词

Metallocene,Manganese,Structure elucidation,Electrochemistry,55Mn NMR spectroscopy

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