Comparative characteristics and enhanced removal of tetracycline and ceftriaxone by Fe3O4-lignin and Fe3O4-carbon-based lignin: Mechanism, thermodynamic evaluation, and DFT calculation

Journal of Molecular Liquids(2023)

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摘要
•Synthesis of eco-friendly lignin and carbon-based lignin magnetic composites.•Removal of tetracycline (TRC) and ceftriaxone (CEF) by Fe3O4-lignin and Fe3O4-carbon-based lignin.•Electrostatic attraction, hydrophobic, hydrogen bond, and π-π interaction adsorption mechanisms.•Adsorption of TRC was endothermic while that of CEF was exothermic.•DFT calculations and reusability.
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关键词
Lignin,Carbon-based lignin, antibiotics,Adsorption mechanisms,Thermodynamics
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