Zwitterion or diradicaloid? The case of diazenium betaines derived from DPPH

JOURNAL OF MOLECULAR STRUCTURE(2023)

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摘要
Starting from the well-known stable free radical 2,2-diphenyl-1-picrylhydrazyl (DPPH), novel diazenium betaines were obtained. These were characterized by NMR, IR, MS, ESR, CV, UV-Vis, and single crystal X-ray diffraction. A discussion about their diradicaloid character is also described.(c) 2022 Elsevier B.V. All rights reserved.
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关键词
Hydrazyl,DPPH,Betaine,Free radical,Diradicaloid,Zwitterion
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