Switching the ESIPT and TICT process of DP-HPPI via intermolecular hydrogen bonding

Hongyan Mu, Yuhang Sun,Jiaan Gao,Chao Xin,Huifang Zhao,Guangyong Jin,Hui Li

Journal of Molecular Structure（2023）

引用 4|浏览5

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摘要

•DP-HPPI undergoes reversible ESIPT process in DCM.•ESIPT is prohibited due to the involvement of intermolecular hydrogen bonding in ACN.•Intermolecular hydrogen bonding initiates the TICT process of DP-HPPI in ACN.

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关键词

Intermolecular hydrogen bonding,Excited-state intramolecular proton transfer,Twisted intramolecular charge transfer,Potential energy curves

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