Choose your leaving group: selective photodeprotection in a mixture of pHP-caged compounds by VIPER excitation

Luuk J. G. W. van Wilderen,Daniela Kern-Michler,Carsten Neumann,Matiss Reinfelds,Jan von Cosel,Maximiliane Horz,Irene Burghardt,Alexander Heckel,Jens Bredenbeck

Chemical science（2023）

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摘要

Combine IR selectivity with UV induced photochemistry. Tune the wavenumber of the IR excitation to the resonance of a specific photocage isotopologue and release the desired leaving group.

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关键词

selective photodeprotection,compounds,excitation,hp-caged

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