Expanding the 'aplysinospin cascade' through DNA-templated [2+2] photocycloaddition.
Chemical communications (Cambridge, England)(2023)
摘要
Inspired by the unique ability of nucleic acids to template chemical transformations that are otherwise impossible in solution, we embarked on the generalisation of our DNA-templated [2+2] photo-induced homo- and heterodimerization of aplysinopsins. Our process ensures a straightforward access to cyclobutane containing natural products and analogues thereof. Most importantly, this conceptual biomimetic achievement presents interesting arguments to build a biosynthetic scenario.
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关键词
‘aplysinospin cascade,dna-templated
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