Unveiling light effect on formation of trisulfur radicals in lithium-sulfur batteries.

is the important electrochemical intermediate in Li-S batteries of highly solvating solvents. Herein, the dissociation of into is deeply studied. light is proven to promote the formation of from the dissociation of . Accordingly, a strategy of pre-introducing highly active into DMSO-based electrolyte is proposed to activate sulfur cathodes of Li-S batteries.