Briavioid D, a rare 7β,8β-epoxybriarane from Briareum violaceum

Thanh Hao Huynh,Chou-Yuan Ko,Hsin-Tzu Liu, Yen-Po Chen,Mingzi M. Zhang,Lun Kelvin Tsou,Zhi-Hong Wen,Su-Ying Chien,Ping-Jyun Sung

Tetrahedron Letters（2023）

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摘要

•A rare 7β,8β-epoxybriarane, briavioid D (1), was isolated from Briareum violaceum.•The structure of briarane 1 was determined by a single-crystal X-ray diffraction analysis.•Briavioid D is the first example of briarane analog possessing a 7,8‑epoxy group in the γ-lactone moiety.

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关键词

Briareum violaceum,Briavioid,Briarane,X-ray,iNOS

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