Chitosan-supported metal nanocatalysts for the reduction of nitroaromatics.

The second most abundant natural polymer in the earth's crust is chitosan (CS). The unique physical, chemical, structural, and mechanical features of this natural polymer have led to its increased application in a variety of fields such as medicine, catalysis, removal of pollutants, etc. To eliminate various pollutants, it is preferable to employ natural compounds as their use aids the removal of contaminants from the environment. Consequently, employing CS to eliminate contaminants is a viable choice. For this aim, CS can be applied as a template and support for metal nanoparticles (MNPs) and prevent the accumulation of MNPs as well as a reducing and stabilizing agent for the fabrication of MNPs. Among the pollutants present in nature, nitro compounds are an important and wide category of biological pollutants. 4-Nitrophenol (4-NP) is one of the nitro pollutants. There are different ways for the removal of 4-NP, but the best and most effective method for this purpose is the application of a metallic catalyst and a reducing agent. In this review, we report the recent developments regarding CS-supported metallic (nano)catalysts for the reduction of nitroaromatics such as nitrophenols, nitroaniline compounds, nitrobenzene, etc. in the presence of reducing agents. The metals investigated in this study include Ag, Au, Ni, Cu, Ru, Pt, Pd, etc.