Ligand-enabled Silver-Catalyzed Carbene Insertion into the N–H Bond of Aliphatic and Electron-Rich Aromatic Amines

Linxuan Li,Paramasivam Sivaguru,Xinyue Han,Swastik Karmakar,Xihe Bi

Organic chemistry frontiers（2023）

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摘要

The stable effect of tris(pyrazolyl)borate ligand and 1,2-diaminocyclohexane ligand on the silver metal center was used respectively, to realize the efficient N–H bond insertion reaction of carbene to aliphatic amines and aromatic amines.

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