Complex formation of Cucurbit[6]uril with DABCO and DABCO derivatives: An experimental and DFT study
crossref(2023)
摘要
The complex formation of Cucurbit[6]uril with DABCO and DABCO derivatives in solution has been studied using calorimetric titrations. For a better understanding of factors influencing the complex formation, several DABCO derivatives have been synthesized. All compounds have been characterized. Inclusion complex formation could not be observed. Even with dumbbell derivatives of DABCO threading through the Cucurbit[6]uril cavity does not occur. As a result, no rotaxanes have been formed in solution. These results are in accordance with DFT calculations.
更多查看译文
AI 理解论文
溯源树
样例
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要