The Heteroepitaxy of Thick Β-Ga2o3 Film on Sapphire Substrate with a Β-(Alxga1−x)2o3 Intermediate Buffer Layer

A high aluminum (Al) content β-(AlxGa1−x)2O3 film was synthesized on c-plane sapphire substrate using the gallium (Ga) diffusion method. The obtained β-(AlxGa1−x)2O3 film had an average thickness of 750 nm and a surface roughness of 2.10 nm. Secondary ion mass spectrometry results indicated the homogenous distribution of Al components in the film. The Al compositions in the β-(AlxGa1−x)2O3 film, as estimated by X-ray diffraction, were close to those estimated by X-ray photoelectron spectroscopy, at ~62% and ~61.5%, respectively. The bandgap of the β-(AlxGa1−x)2O3 film, extracted from the O 1s core-level spectra, was approximately 6.0 ± 0.1 eV. After synthesizing the β-(AlxGa1−x)2O3 film, a thick β-Ga2O3 film was further deposited on sapphire substrate using carbothermal reduction and halide vapor phase epitaxy. The β-Ga2O3 thick film, grown on a sapphire substrate with a β-(AlxGa1−x)2O3 buffer layer, exhibited improved crystal orientation along the (-201) plane. Moreover, the scanning electron microscopy revealed that the surface quality of the β-Ga2O3 thick film on sapphire substrate with a β-(AlxGa1−x)2O3 intermediate buffer layer was significantly improved, with an obvious transition from grain island-like morphology to 2D continuous growth, and a reduction in surface roughness to less than 10 nm.