Active metal dependent side reactions for the reductive amination of furfural

Huanjiang Wang, Yuchen Zhang, Dan Luo,He Wang,Yurong He,Fei Wang,Xiaodong Wen

Molecular Catalysis（2023）

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摘要

•Co-, Ni-, and Ru-based catalysts show good primary amine selectivity.•The competitive adsorption of FAM and H2 suppresses its excessive hydrogenation.•The adsorption energies of FAM on Co, Ni, and Ru surfaces are calculated.•The activation energy is not the key factor in determining the FAM hydrogenation.

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关键词

Heterogeneous catalysis,Reductive amination,Excessive hydrogenation,Competitive adsorption,H/D exchange

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