Partially Fluorinated Poly(arylene-Alkane)s Containing Cobaltocenium for Alkaline-Stable Anion Exchange Membranes.

Run Zhang,Xiaoyu Zhao,Wenhao Li,Huidong Qian,Hui Yang

Chemical communications（2023）

Cited 3|Views5

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Abstract

Alkali-resistant metal-based cationic polyelectrolytes are designed as anion exchange membranes. After grafting aminocobaltocene hexafluorophosphates onto partially fluorinated ether-free poly(arylene-alkane)s via a simple nucleophilic substitution reaction, the membrane exhibits excellent chemical, thermal and mechanical stability, high hydroxide conductivity, as well as durability of single cells for 400 h.

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