Template synthesis of an intermediate in silver salt metathesis using a calix[4]arene-based diphosphine ligand.
Dalton transactions (Cambridge, England : 2003)（2023）
摘要
The synthesis and solid-state characterisation of the heterobimetallic rhodium(III)/silver(I) complex [Rh(2,2'-biphenyl)(CxP)Cl]⊃Ag is described, where CxP is a -spanning calix[4]arene-based diphosphine and the silver cation is datively bound to the chloride ligand within the cavity of the macrocycle.
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关键词
silver salt metathesis,ligand,synthesis,]arene-based
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