Chain photosolvation of trans,trans,trans-[Ptiv(py)2(N3)2(OH)2] complex prospective as a light-activated antitumor agent

Grigory I. Zhdankin,Vjacheslav P. Grivin,Victor F. Plyusnin,Pavel A. Tkachenko,Danila B. Vasilchenko,Evgeni M. Glebov

MENDELEEV COMMUNICATIONS（2023）

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摘要

The photochemistry of a potential light-activated anticancer complex, trans,trans,trans-[PtIV(py)2(N3)2(OH)2], was explored by steady-state and laser flash photolysis. The photolysis was a multistage process with the formation of complexes trans- [PtIV(py)2(N3)(OH)2(H2O)]+ and/or trans-[PtIV(py)2(N3)(OH)3] due to chain photoaquation at the first stage. OH N N3 Pt N3 OH N hn Chain process OH N N3 Pt N3 OH H2O/OH

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关键词

photochemistry,photoactivated chemotherapy,platinum complexes,photochemical chain reactions

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