Spectral properties of IR-filamentation in air induced by 1 ps pulses for coherent anti-Stokes Raman scattering

We investigate the spectral properties of ps laser-induced filamentation in air using an ultrafast thin-disk based amplifier at a central wavelength of 1030 nm with a maximum pulse energy of 60 mJ at a repetition rate of 1 kHz. We show that the spectrum induced by filamentation in air is sufficiently broad to excite ro-vibrational Raman transitions in N2, O2 and CH4. The excitation is probed with the second harmonic (515 nm) to generate CARS signals in air. Furthermore, we investigate the influence of optical windows on the CARS signal for applications in combustion and gasification diagnostics.(c) 2023 Optica Publishing Group under the terms of the Optica Open Access Publishing Agreement